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Studies of nanoparticle reinforced polymer coatings for trace gas detection

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Date Issued:
2013
Summary:
With the goal of improving chemical detection methods for buried improvised explosive devices (IED’s), the intention of this study is to show that functionalized nano-particles improve the sensing properties of a polymer applied to gas sensors. The approach was reinforcing the polymer, Nafion, with acid-functionalized carbon nanotubes (CNT’s). Ammonia was chosen as the analyte for its similarity to IED byproducts without the dangers of toxicity or explosion. Two sensor platforms were investigated: Quartz crystal microbalances (QCM’s) and microcantilevers (MC’s). Preliminary evaluation of treated QCM’s, via frequency analyzer, showed improvements in sensitivity and fast reversal of adsorption; and suggested increased stability. Tests with coated MC’s also supported the findings of QCM tests. Amplitude response of MC’s was on average 4 times greater when the Nafion coating contained CNT’s. Quantitative QCM testing with gas-flow meters showed that with CNT inclusion: the average number of moles adsorbed increased by 35% (>1.2 times frequency response); sensitivity improved by 0.63 Hz/ppt on average; although the detection threshold decreased marginally; but reusability was much better after extended exposures to concentrated ammonia.
Title: Studies of nanoparticle reinforced polymer coatings for trace gas detection.
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Name(s): Davis, Charles, author
Mahfuz, Hassan, Thesis advisor
College of Engineering and Computer Science, Degree grantor
Department of Ocean and Mechanical Engineering
Type of Resource: text
Genre: Electronic Thesis Or Dissertation
Issuance: single unit
Date Created: Fall 2013
Date Issued: 2013
Publisher: Florida Atlantic University
Physical Form: Online Resource
Extent: 54p.
Language(s): English
Summary: With the goal of improving chemical detection methods for buried improvised explosive devices (IED’s), the intention of this study is to show that functionalized nano-particles improve the sensing properties of a polymer applied to gas sensors. The approach was reinforcing the polymer, Nafion, with acid-functionalized carbon nanotubes (CNT’s). Ammonia was chosen as the analyte for its similarity to IED byproducts without the dangers of toxicity or explosion. Two sensor platforms were investigated: Quartz crystal microbalances (QCM’s) and microcantilevers (MC’s). Preliminary evaluation of treated QCM’s, via frequency analyzer, showed improvements in sensitivity and fast reversal of adsorption; and suggested increased stability. Tests with coated MC’s also supported the findings of QCM tests. Amplitude response of MC’s was on average 4 times greater when the Nafion coating contained CNT’s. Quantitative QCM testing with gas-flow meters showed that with CNT inclusion: the average number of moles adsorbed increased by 35% (>1.2 times frequency response); sensitivity improved by 0.63 Hz/ppt on average; although the detection threshold decreased marginally; but reusability was much better after extended exposures to concentrated ammonia.
Identifier: FA0004014 (IID)
Note(s): Includes bibliography.
Thesis (M.S.)--Florida Atlantic University, 2013.
Subject(s): Conducting polymers
Detectors -- Technological innovations
Explosives -- Detection
Nanocomposites (Materials)
Nanostructured materials
Smart materials
Held by: Florida Atlantic University Digital Library
Sublocation: Boca Raton, Fla.
Persistent Link to This Record: http://purl.flvc.org/fau/fd/FA0004014
Restrictions on Access: All rights reserved by the source institution
Restrictions on Access: http://rightsstatements.org/vocab/InC/1.0/
Host Institution: FAU