You are here
Adhesion of calcareous deposits formed on steel surfaces under cathodic polarization
- Date Issued:
- 1991
- Summary:
- A procedure has been devised to characterize the adhesion of calcareous deposits formed upon steel in association with cathodic polarization in seawater. This involved bending the substrate in-situ and characterization of deposit debonding in terms of visual appearance, changes in the cathodic current density and the net charge transferred in association with film disruption. Specific attention has been focused upon the influence of exposure time, applied potential, flow rate, temperature, substrate surface finish and electrolyte type upon deposit adhesion. Presence of a Mg-rich, inner film as well as the impingement of CaCO3 particles enhanced the adhesion of calcareous deposits. Electrostatic forces, Van der Waals attraction, and chemical alteration of precipitates could be important factors contributing to deposit adhesion.
Title: | Adhesion of calcareous deposits formed on steel surfaces under cathodic polarization. |
87 views
41 downloads |
---|---|---|
Name(s): |
Luo, Jiunn-Shyong Florida Atlantic University, Degree grantor Hartt, William H., Thesis advisor College of Engineering and Computer Science Department of Ocean and Mechanical Engineering |
|
Type of Resource: | text | |
Genre: | Electronic Thesis Or Dissertation | |
Date Issued: | 1991 | |
Publisher: | Florida Atlantic University | |
Place of Publication: | Boca Raton, Fla. | |
Physical Form: | application/pdf | |
Extent: | 185 p. | |
Language(s): | English | |
Summary: | A procedure has been devised to characterize the adhesion of calcareous deposits formed upon steel in association with cathodic polarization in seawater. This involved bending the substrate in-situ and characterization of deposit debonding in terms of visual appearance, changes in the cathodic current density and the net charge transferred in association with film disruption. Specific attention has been focused upon the influence of exposure time, applied potential, flow rate, temperature, substrate surface finish and electrolyte type upon deposit adhesion. Presence of a Mg-rich, inner film as well as the impingement of CaCO3 particles enhanced the adhesion of calcareous deposits. Electrostatic forces, Van der Waals attraction, and chemical alteration of precipitates could be important factors contributing to deposit adhesion. | |
Identifier: | 12271 (digitool), FADT12271 (IID), fau:9175 (fedora) | |
Collection: | FAU Electronic Theses and Dissertations Collection | |
Note(s): |
College of Engineering and Computer Science Thesis (Ph.D.)--Florida Atlantic University, 1991. |
|
Subject(s): |
Sea-water corrosion Marine steel Cathodic protection Adhesives |
|
Held by: | Florida Atlantic University Libraries | |
Persistent Link to This Record: | http://purl.flvc.org/fcla/dt/12271 | |
Sublocation: | Digital Library | |
Use and Reproduction: | Copyright © is held by the author, with permission granted to Florida Atlantic University to digitize, archive and distribute this item for non-profit research and educational purposes. Any reuse of this item in excess of fair use or other copyright exemptions requires permission of the copyright holder. | |
Use and Reproduction: | http://rightsstatements.org/vocab/InC/1.0/ | |
Host Institution: | FAU | |
Is Part of Series: | Florida Atlantic University Digital Library Collections. |