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Toward the synthesis of organic moieties for use in luminescent lanthanide materials
| Title: | Toward the synthesis of organic moieties for use in luminescent lanthanide materials: from benzodithiophene based linkers to a series of 2,3 pyridinedicarboxylate coordination polymers. |
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| Name(s): |
Ramirez, Amanda Lyn Staggers. Charles E. Schmidt College of Science Department of Chemistry and Biochemistry |
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| Type of Resource: | text | |
| Genre: | Electronic Thesis Or Dissertation | |
| Date Issued: | 2013 | |
| Publisher: | Florida Atlantic University | |
| Physical Form: | electronic | |
| Extent: | xii, 61 p. : ill. (some col.) | |
| Language(s): | English | |
| Summary: | The main focus of this thesis is to present the structural and photophysical characteristics of the coordination polymers [Ln(C7H3NO4)(C7H4NO4)(H2O)]n (Ln is Pr, Nd, Sm, Eu, and Tb), as well as attempting to synthesize the novel organic linker 4,4'(4,8-Dihydrobenzo[1,2-b:4,5-b']dithiophene-4,8-diyl)dibenzoic acid (BDTDC). Various lanthanide salts were coordinated with 2,3-pyridinecarboxylate (2,3- pydc) via hydrothermal synthesis. ... Progress was made toward the synthesis of a novel metal-organic framework linker BDTDC. Synthesis of the intermediate benzo[1,2-b:4,5-b']dithiophene as well as the determination of the crystal structure, were performed successfully and are reported herein. | |
| Identifier: | 863701784 (oclc), 3362561 (digitool), FADT3362561 (IID), fau:4209 (fedora) | |
| Note(s): |
by Amanda Lyn Staggeer Ramirez. Thesis (M.S.)--Florida Atlantic University, 2013. Includes bibliography. Mode of access: World Wide Web. System requirements: Adobe Reader. |
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| Subject(s): |
Metathesis (Chemistry) Supramolecular chemistry Organic compounds -- Synthesis Macromolecules -- Synthesis |
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| Persistent Link to This Record: | http://purl.flvc.org/fcla/dt/3362561 | |
| Use and Reproduction: | http://rightsstatements.org/vocab/InC/1.0/ | |
| Host Institution: | FAU |
